New porphyrin derivatives for phosphate anion sensing in both organic and aqueous media.
نویسندگان
چکیده
New porphyrin-based anion receptors have been prepared from meso-tetrakis(pentafluorophenyl)porphyrin () and diamine derivatives. These receptors (compounds ) interact preferentially with phosphate anions both in organic solutions and in basic aqueous media when coated on gold piezoelectric quartz crystals. A single crystal X-ray structure of the bis-HF complex of a imine derivative of was obtained; it serves to highlight the main interactions between the anion and cation receptors in the solid state.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 11 شماره
صفحات -
تاریخ انتشار 2014